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Gold(I)-catalyzed intermolecular hydroarylation of allenes with nucleophilic arenes: scope and limitations
The addition of nucleophilic methoxyarenes to allenes proceeds at room temperature in dichloromethane with a catalytic amount of phosphite-gold(I) precatalyst and silver additive. The addition is regioselective for the allene terminus, and generates E-allylation products without the need for prefunc...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2009
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3079221/ https://ncbi.nlm.nih.gov/pubmed/21512612 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.10.110 |
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