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Enantioselective Total Synthesis and Confirmation of the Absolute and Relative Stereochemistry of Streptorubin B
The enantioselective total synthesis of the pyrrolophane natural product streptorubin B is described. Key steps in the concise route include application of a one-pot enantioselective aldol cyclization/Wittig reaction and an anionic oxy-Cope rearrangement to forge the crucial 10-membered ring. Compar...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3073088/ https://ncbi.nlm.nih.gov/pubmed/21166419 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja109165f |
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