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Base-Mediated Intermolecular sp(2) C-H Bond Arylation via Benzyne Intermediates
A transition-metal-free method for arylation of heterocycle and arene carbon-hydrogen bonds by aryl chlorides and fluorides has been developed. The reactions proceed via aryne intermediates and are highly regioselective with respect to the C-H bond coupling component.
Tallennettuna:
| Päätekijät: | , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2011
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3065930/ https://ncbi.nlm.nih.gov/pubmed/21384889 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200184b |
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