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Base-Mediated Intermolecular sp(2) C-H Bond Arylation via Benzyne Intermediates

A transition-metal-free method for arylation of heterocycle and arene carbon-hydrogen bonds by aryl chlorides and fluorides has been developed. The reactions proceed via aryne intermediates and are highly regioselective with respect to the C-H bond coupling component.

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Bibliografiska uppgifter
Huvudupphovsmän: Truong, Thanh, Daugulis, Olafs
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2011
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3065930/
https://ncbi.nlm.nih.gov/pubmed/21384889
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200184b
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