Characterization of a Tricationic Trigonal Bipyramidal Iron(IV) Cyanide Complex, with a Very High Reduction Potential, and Its Iron(II) and Iron(III) Congeners

Currently, there are only a handful of synthetic S = 2 oxoiron(IV) complexes. These serve as models for the high-spin (S = 2) oxoiron(IV) species that have been postulated, and confirmed in several cases, as key intermediates in the catalytic cycles of a variety of non-heme oxygen activating enzymes...

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主要な著者: England, Jason, Farquhar, Erik R., Guo, Yisong, Cranswick, Matthew A., Ray, Kallol, Münck, Eckard, Que, Lawrence
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
Article
オンライン･アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3065519/
https://ncbi.nlm.nih.gov/pubmed/21381646
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic102094d
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