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Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(ii)

Monometallic complexes based on 3d transition metal ions in certain axial coordination environments can exhibit appreciably enhanced magnetic anisotropy, important for memory applications, due to stabilisation of an unquenched orbital moment. For high-spin trigonal bipyramidal Ni(ii), if competing s...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Marriott, Katie E. R., Bhaskaran, Lakshmi, Wilson, Claire, Medarde, Marisa, Ochsenbein, Stefan T., Hill, Stephen, Murrie, Mark
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5508675/
https://ncbi.nlm.nih.gov/pubmed/28757973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02854j
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