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Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(ii)
Monometallic complexes based on 3d transition metal ions in certain axial coordination environments can exhibit appreciably enhanced magnetic anisotropy, important for memory applications, due to stabilisation of an unquenched orbital moment. For high-spin trigonal bipyramidal Ni(ii), if competing s...
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Publicado no: | Chem Sci |
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Main Authors: | , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Royal Society of Chemistry
2015
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5508675/ https://ncbi.nlm.nih.gov/pubmed/28757973 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02854j |
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