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Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(ii)
Monometallic complexes based on 3d transition metal ions in certain axial coordination environments can exhibit appreciably enhanced magnetic anisotropy, important for memory applications, due to stabilisation of an unquenched orbital moment. For high-spin trigonal bipyramidal Ni(ii), if competing s...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5508675/ https://ncbi.nlm.nih.gov/pubmed/28757973 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02854j |
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