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Efficient, Highly Stereoselective Synthesis of α-Keto-deoxy-D-glycero-D-galacto-nonulosonic Acid (KDN) Glycosides by Means of the 4,5-O-Carbonate Protecting Group
[Image: see text] A 1-adamantyl thioglycoside derivative of KDN, derived from N-acetylneuraminic acid, carrying a 3,4-O-carbonate protecting group is a highy efficient and α-selective KDN donor on activation with NIS and TfOH in dichloromethane and acetonitrile at −78 °C. Glycosylations conducted wi...
שמור ב:
| Main Authors: | , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2010
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3064762/ https://ncbi.nlm.nih.gov/pubmed/20333634 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200907178 |
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