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Use of Phenols as Nucleophiles in the Zbiral Oxidative Deamination of N-Acetyl Neuraminic Acid. Isolation and Characterization of Tricyclic 3-Keto-2-Deoxy-nonulosonic Acid (KDN) Derivatives via an Intermediate Vinyl Diazonium Ion
It is well established that the N-nitrososamide derived from peracetylated derivatives of N-acetylneuraminic acid on treatment with a mixture of sodium isopropoxide and trifluoroethanol, followed by addition of acetic acid gives an oxidative deamination product in which the AcN(NO)-C5 bond is replac...
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| Опубликовано в: : | J Org Chem |
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| Главные авторы: | , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6858517/ https://ncbi.nlm.nih.gov/pubmed/31608634 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02279 |
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