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Use of Phenols as Nucleophiles in the Zbiral Oxidative Deamination of N-Acetyl Neuraminic Acid. Isolation and Characterization of Tricyclic 3-Keto-2-Deoxy-nonulosonic Acid (KDN) Derivatives via an Intermediate Vinyl Diazonium Ion

It is well established that the N-nitrososamide derived from peracetylated derivatives of N-acetylneuraminic acid on treatment with a mixture of sodium isopropoxide and trifluoroethanol, followed by addition of acetic acid gives an oxidative deamination product in which the AcN(NO)-C5 bond is replac...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Hawsawi, Mohammed, Wickramasinghe, Anura, Crich, David
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6858517/
https://ncbi.nlm.nih.gov/pubmed/31608634
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02279
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