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Catalytic Asymmetric Synthesis of Allylic Thiol Derivatives
[Image: see text] The palladium(II) complex [(Rp,S)-COP-Cl](2) and its enantiomer catalyze the rearrangement of linear prochiral O-allyl carbamothioates under mild conditions to provide branched S-allyl carbamothioates in high yield and high enantiomeric purity.
Sparad:
| Huvudupphovsmän: | , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2008
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3064473/ https://ncbi.nlm.nih.gov/pubmed/18336036 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8002942 |
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