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Pentavalent Organo-Vanadates as Transition State Analogues for Phosphoryl Transfer Reactions

Pentavalent organo-vanadates have been put forth as transition state analogues for a variety of phosphoryl transfer reactions. In particular, uridine 2′,3′-cyclic vanadate (U>v) has been proposed to resemble the transition state during catalysis by ribonuclease A (RNase A). Here, this hypothesis...

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Detalhes bibliográficos
Main Authors: Messmore, June M., Raines, Ronald T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2000
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3058181/
https://ncbi.nlm.nih.gov/pubmed/21423825
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0021058
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