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Synthesis of (±)-7-Hydroxylycopodine

[Image: see text] A 6 step synthesis of (±)-7-hydroxylycopodine has been achieved in 5% overall yield. In the key step, a Prins cyclization of a bicyclic keto alkyne in 60% H(2)SO(4) forms a tricyclic dihydroxy amino ketone.

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Détails bibliographiques
Auteurs principaux: Lin, Hong-Yu, Snider, Barry B.
Format: Artigo
Langue:Inglês
Publié: 2011
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3056437/
https://ncbi.nlm.nih.gov/pubmed/21271726
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200119h
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