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Synthesis of (±)-7-Hydroxylycopodine
A seven-step synthesis of (±)-7-hydroxylycopodine that proceeds in 5% overall yield has been achieved. The key step is a Prins reaction in 60% sulfuric acid that gave the key tricyclic intermediate with complete control of the ring fusion stereochemistry. A one-pot procedure orthogonally protected t...
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| Autores principales: | , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2012
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3393807/ https://ncbi.nlm.nih.gov/pubmed/22443298 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo300353t |
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