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Synthesis of 7-Epineoptilocaulin, Mirabilin B, and Isoptilocaulin. A Unified Biosynthetic Proposal for the Ptilocaulin and Batzelladine Alkaloids. Synthesis and Structure Revision of Netamines E and G
[Image: see text] Addition of guanidine to a 6-methylhexahydroindenone in MeOH at reflux afforded 7-epineoptilocaulin. A similar reaction with a 6-propylhexahydroindenone afforded netamine E. MnO(2) oxidation of 7-epineoptilocaulin and netamine E afforded mirabilin B and netamine G, respectively. Th...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2593083/ https://ncbi.nlm.nih.gov/pubmed/18928319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801956w |
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