Unified Total Synthesis of Pyrroloazocine Indole Alkaloids Sheds Light on Their Biosynthetic Relationship

[Image: see text] The total synthesis of seven members of the lapidilectine and grandilodine family of alkaloids has been accomplished in racemic and enantiopure form without protection/deprotection of functional groups. The two key steps, an 8-endo-dig hydroarylation and a 6-exo-trig photoredox cyc...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Miloserdov, Fedor M., Kirillova, Mariia S., Muratore, Michael E., Echavarren, Antonio M.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2018
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5920919/
https://ncbi.nlm.nih.gov/pubmed/29432680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b13484
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