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RNA methylation by Radical SAM enzymes RlmN and Cfr proceeds via methylene transfer and hydride shift

RlmN and Cfr are Radical SAM enzymes that modify a single adenosine nucleotide—A2503—in 23S ribosomal RNA. This nucleotide is positioned within the peptidyl transferase center of the ribosome, which is a target of numerous antibiotics. An unusual feature of these enzymes is their ability to carry ou...

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Bibliografiske detaljer
Main Authors: Yan, Feng, Fujimori, Danica Galonić
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2011
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3054002/
https://ncbi.nlm.nih.gov/pubmed/21368151
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1017781108
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