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A Highly Reactive Dicationic Iridium(III) Catalyst for Polarized Nazarov Cyclization
[Image: see text] Pushing the Nazarov Envelope A new electrophilic complex [IrBr(CO)(diethylisopropylidene malonate)((R)-(+)-BINAP)](SbF(6))(2) (2) exhibits unusual activity in the catalysis of polarized Nazarov cyclization. Aryl vinyl ketones that show poor reactivity with well-known catalysts such...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3032601/ https://ncbi.nlm.nih.gov/pubmed/20358570 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201000100 |
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