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Oxidation-Initiated Nazarov Cyclization of Vinyl Alkoxyallenes
[Image: see text] A mild method for the diastereoselective formation of C(4), C(5)-disubstituted cyclopentenones has been developed, involving formation of a pentadienyl cation via diastereoselective oxidation of a vinyl alkoxyallene. Conrotatory electrocyclization provides the cyclopentenone produc...
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Main Authors: | , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2010
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3032600/ https://ncbi.nlm.nih.gov/pubmed/21155592 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1027255 |
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