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Conjugate Addition-Initiated Nazarov Cyclization

A reaction sequence involving the 1,6-conjugate addition of a nucleophile to a dienyl diketone followed by Nazarov cyclization is described. Several nucleophiles are identified as competent initiators for the sequence. A different reaction outcome is is observed when catalytic amounts of nucleophile...

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Main Authors: Brooks, Joshua L., Caruana, Patrick A., Frontier, Alison J.
Formato: Artigo
Idioma:Inglês
Publicado: 2011
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3178270/
https://ncbi.nlm.nih.gov/pubmed/21780785
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205440x
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