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Mechanism of tungsten-dependent acetylene hydratase from quantum chemical calculations
Acetylene hydratase is a tungsten-dependent enzyme that catalyzes the nonredox hydration of acetylene to acetaldehyde. Density functional theory calculations are used to elucidate the reaction mechanism of this enzyme with a large model of the active site devised on the basis of the native X-ray cry...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
National Academy of Sciences
2010
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3012519/ https://ncbi.nlm.nih.gov/pubmed/21149684 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1014060108 |
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