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Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes

We have investigated both the chemical reduction of (BDI)Nb(V) imido complexes (BDI = HC[C(Me)NAr](2); Ar = 2,6-(i)Pr(2)-C(6)H(3)) to the formal Nb(III) oxidation state and the ability of these Nb(III) complexes to behave as two-electron reductants. The reduction of the Nb(V) species was found to de...

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Autors principals: Tomson, Neil C., Arnold, John, Bergman, Robert G.
Format: Artigo
Idioma:Inglês
Publicat: 2010
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2992439/
https://ncbi.nlm.nih.gov/pubmed/21116450
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om1002528
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