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Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand
Synthesis of the complex (BDI)Nb(N(t)Bu)Cl(2)py (BDI = HC[C(Me)N(2,6-iPr(2)-C(6)H(3))](2)) was achieved in high yield following the treatment of Nb(N(t)Bu)Cl(3)py(2) with Li(BDI)(OEt(2)). Substitution of the chlorides for fluorides was effected by introducing 2.0 equiv of Me(3)SnF in toluene, provid...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2909775/ https://ncbi.nlm.nih.gov/pubmed/20671985 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om1001827 |
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