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Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions

The synthesis and reactivity of dibenzyl cationic tantalum imido complexes is described. The trialkyl tantalum imido compounds Bn(3)Ta=NCMe(3) (1) and Np(3)Ta=NCMe(3) (2) were synthesized as starting materials for the study of dialkyl cationic tantalum imido complexes. Compound 1 undergoes insertion...

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Detalhes bibliográficos
Main Authors: Anderson, Laura L., Schmidt, Joseph A. R., Arnold, John, Bergman, Robert G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2600720/
https://ncbi.nlm.nih.gov/pubmed/19079787
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om060081t
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