Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives

We present a series of compounds by exploiting the unusual 1,4-aryl shift observed for electron-rich 1,3-dithiole-2-thione and tetrathiafulvalene (TTF) derivatives in the presence of perchloric acid. The mechanistic features of this rearrangement are discussed since this synthetic strategy provides...

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Detalhes bibliográficos
Main Authors: Vilela, Filipe, Skabara, Peter J, Mason, Christopher R, Westgate, Thomas D J, Luquin, Asun, Coles, Simon J, Hursthouse, Michael B
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2010
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Full Research Paper
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2981815/
https://ncbi.nlm.nih.gov/pubmed/21085502
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.113
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