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Catalytic Asymmetric Generation of (Z)-Disubstituted Allylic Alcohols
A one-pot method for the direct preparation of enantioenriched (Z)-disubstituted allylic alcohols is introduced. Hydroboration of 1-halo-1-alkynes with dicyclohexylborane, reaction with t-BuLi, and transmetallation with dialkylzinc reagents generates (Z)-disubstituted vinylzinc intermediates. In sit...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2532596/ https://ncbi.nlm.nih.gov/pubmed/18052173 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0762285 |
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