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Accurate proton affinity and gas-phase basicity values for molecules important in biocatalysis

Benchmark quantum calculations of proton affinities and gas phase basicities of molecules relevant to biochemical processes, particulsarly acid/base catalysis, are presented and compared for a variety of multi-level and density-functional quantum models. Included are nucleic acid bases in both keto...

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Detalhes bibliográficos
Main Authors: Moser, Adam, Range, Kevin, York, Darrin M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2970571/
https://ncbi.nlm.nih.gov/pubmed/20942500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp107450n
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