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Mechanism of the Cobalt Oxazoline Palladacycle (COP)-Catalyzed Asymmetric Synthesis of Allylic Esters

The catalytic enantioselective S(N)2′ displacement of (Z)-allylic trichloroacetimidates catalyzed by the palladium(II) complex [COP-OAc](2) is a broadly useful method for the asymmetric synthesis of chiral branched allylic esters. A variety of experiments aimed at elucidating the nature of the catal...

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Hlavní autoři: Cannon, Jeffrey S., Kirsch, Stefan F., Overman, Larry E., Sneddon, Helen F.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2967776/
https://ncbi.nlm.nih.gov/pubmed/20942424
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106688j
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