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Application of a Chiral Scaffolding Ligand in Catalytic Enantioselective Hydroformylation
The synthesis of β-amino-aldehydes has been achieved through enantioselective hydroformylation of PMP-protected allylic amines. The reaction is accomplished by using a scalemic scaffolding ligand that covalently and reversibly binds to the substrate. These ligands behave like chiral auxiliaries beca...
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| Auteurs principaux: | , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2010
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2962579/ https://ncbi.nlm.nih.gov/pubmed/20882977 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107433h |
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