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Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates and Allyl Ethers Using Chiral Diazaphospholane Ligands
Rhodium complexes of diazaphospholane ligands catalyze the asymmetric hydroformylation of N-vinyl carboxamides, allyl ethers and allyl carbamates; products include 1,2- and 1,3-amino aldehydes and 1,3-alkoxy aldehydes. Using glass pressure bottles, short reaction times (generally less than 6 hours),...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2995725/ https://ncbi.nlm.nih.gov/pubmed/20845958 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106674n |
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