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Catalytic Enantioselective Formation of Chiral Bridged Dienes Which Are Themselves Ligands for Enantioselective Catalysis
[Image: see text] This paper reports a method for highly enantioselective Diels-Alder reaction with an acetylene equivalent to produce chiral bridged dienes. These dienes, by coordination to Rh(I), can serve as catalysts for the enantioselective addition of vinyl or aryl groups to α,β-unsaturated ke...
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| Autores principales: | , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2010
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2814301/ https://ncbi.nlm.nih.gov/pubmed/19947622 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9025793 |
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