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Catalytic Enantioselective Diboration of Cyclic Dienes. A Modified Ligand with General Utility
[Image: see text] The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4 diol whereas homologation can be used to deliver a chiral 1,6 diol.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3219059/ https://ncbi.nlm.nih.gov/pubmed/21932816 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201321k |
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