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A multigram chemical synthesis of the γ-secretase inhibitor LY411575 and its diastereoisomers

An improved chemical synthesis of N-2((2S)-2-(3,5-difluorophenyl)-2-hydroxyethanoyl)-N1-((7S)-5-methyl-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-L-alaninamide (LY411,575, 9a), a known γ-secretase inhibitor, is described. The key synthetic steps, which used no chiral chromatography in the entire...

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Detalhes bibliográficos
Main Authors: Fauq, Abdul H., Simpson, Katherine, Maharvi, Ghulam M., Golde, Todd, Das, Pritam
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2962444/
https://ncbi.nlm.nih.gov/pubmed/17897827
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmcl.2007.07.062
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