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Stereoretentive Suzuki-Miyaura Coupling of Haloallenes Enables Fully Stereocontrolled Access to (−)-Peridinin

[Image: see text] Stimulated by the substantial challenge of synthesizing the complex and sensitive stereogenic allene-containing core of (−)-peridinin, the first stereocontrolled coupling of haloallenes with boronic acids has been achieved. This new method and the principles that emerged during its...

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Detalhes bibliográficos
Main Authors: Woerly, Eric M., Cherney, Alan H., Davis, Erin K., Burke, Martin D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2957181/
https://ncbi.nlm.nih.gov/pubmed/20441218
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja102721p
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