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Axial shielding of Pd(II) complexes enables perfect stereoretention in Suzuki-Miyaura cross-coupling of Csp(3) boronic acids
Stereocontrolled Csp(3) cross-coupling can fundamentally change the types of chemical structures that can be mined for molecular functions. Although considerable progress in achieving the targeted chemical reactivity has been made, controlling stereochemistry in Csp(3) cross-coupling remains challen...
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| 發表在: | Nat Commun |
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| Main Authors: | , , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Nature Publishing Group UK
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6427018/ https://ncbi.nlm.nih.gov/pubmed/30894535 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-09249-z |
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