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Enantioselective Synthesis of (Z)-1,2-anti-2,5-anti-Triol Monosilyl Ethers Using a Cross-Metathesis Allylboration Sequence

[Image: see text] The enantioselective synthesis of (Z)-1,2-anti-2,5-anti-triol monosilyl ethers via a two-step sequence involving olefin cross-metathesis of β-alkoxyallylboronate 4 and subsequent allylboration of the derived bisboryl intermediate 6 provides triol monoethers 7 with good to excellent...

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Detalhes bibliográficos
Main Authors: Winbush, SusAnn M., Roush, William R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2945398/
https://ncbi.nlm.nih.gov/pubmed/20806914
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101789g
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