Загрузка...
Enantioselective Synthesis of (Z)-2-Methyl-1,5-anti- and (E)-2-Methyl-1,5-anti-Pentenediols Via an Allene Hydroboration-Double Allylboration Reaction Sequence
Kinetic controlled hydroboration of allenylboronate 5 followed by double allylboration with resulting allylborane (Z)-7 gave (Z)-2-methyl-1,5-anti-pentenediols 6 in good yield and high enantioselectivity in the presence of 10% BF(3)•OEt(2) as the catalyst in the second allylboration step. Under ther...
Сохранить в:
| Главные авторы: | , |
|---|---|
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2013
|
| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3733567/ https://ncbi.nlm.nih.gov/pubmed/23758559 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4033633 |
| Метки: |
Добавить метку
Нет меток, Требуется 1-ая метка записи!
|