Загрузка...

Enantioselective Synthesis of (Z)-2-Methyl-1,5-anti- and (E)-2-Methyl-1,5-anti-Pentenediols Via an Allene Hydroboration-Double Allylboration Reaction Sequence

Kinetic controlled hydroboration of allenylboronate 5 followed by double allylboration with resulting allylborane (Z)-7 gave (Z)-2-methyl-1,5-anti-pentenediols 6 in good yield and high enantioselectivity in the presence of 10% BF(3)•OEt(2) as the catalyst in the second allylboration step. Under ther...

Полное описание

Сохранить в:
Библиографические подробности
Главные авторы: Chen, Ming, Roush, William R.
Формат: Artigo
Язык:Inglês
Опубликовано: 2013
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3733567/
https://ncbi.nlm.nih.gov/pubmed/23758559
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4033633
Метки: Добавить метку
Нет меток, Требуется 1-ая метка записи!