Facile C-H bond cleavage via a proton coupled electron transfer involving a C-H⋯Cu(II) interaction

The present study provides mechanistic details of a mild aromatic C-H activation effected by a copper(II) center ligated in a triazamacrocylic ligand, affording equimolar amounts of Cu(III)-aryl species and Cu(I) as reaction products. At low-temperatures the Cu(II) complex 1 forms a 3-center 3-elect...

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Detalhes bibliográficos
Main Authors: Ribas, Xavi, Calle, Carlos, Poater, Albert, Casitas, Alicia, Gómez, Laura, Xifra, Raül, Parella, Teodor, Benet-Buchholz, Jordi, Schweiger, Arthur, Mitrikas, George, Solà, Miquel, Llobet, Antoni, Stack, T. Daniel P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2937838/
https://ncbi.nlm.nih.gov/pubmed/20712320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101599e
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