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Au(iii)-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis

Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C–O and C–N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C–O an...

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書誌詳細
出版年:Chem Sci
主要な著者: Serra, Jordi, Parella, Teodor, Ribas, Xavi
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2017
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5452266/
https://ncbi.nlm.nih.gov/pubmed/28572904
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc03699f
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