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Facile C-H bond cleavage via a proton coupled electron transfer involving a C-H⋯Cu(II) interaction
The present study provides mechanistic details of a mild aromatic C-H activation effected by a copper(II) center ligated in a triazamacrocylic ligand, affording equimolar amounts of Cu(III)-aryl species and Cu(I) as reaction products. At low-temperatures the Cu(II) complex 1 forms a 3-center 3-elect...
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| Главные авторы: | , , , , , , , , , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2010
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2937838/ https://ncbi.nlm.nih.gov/pubmed/20712320 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101599e |
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