Facile C-H bond cleavage via a proton coupled electron transfer involving a C-H⋯Cu(II) interaction

The present study provides mechanistic details of a mild aromatic C-H activation effected by a copper(II) center ligated in a triazamacrocylic ligand, affording equimolar amounts of Cu(III)-aryl species and Cu(I) as reaction products. At low-temperatures the Cu(II) complex 1 forms a 3-center 3-elect...

Celý popis

Uloženo v:
Podrobná bibliografie
Hlavní autoři: Ribas, Xavi, Calle, Carlos, Poater, Albert, Casitas, Alicia, Gómez, Laura, Xifra, Raül, Parella, Teodor, Benet-Buchholz, Jordi, Schweiger, Arthur, Mitrikas, George, Solà, Miquel, Llobet, Antoni, Stack, T. Daniel P.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2937838/
https://ncbi.nlm.nih.gov/pubmed/20712320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101599e
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!

Podobné jednotky