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Study of Proton Coupled Electron Transfer in a Biomimetic Dimanganese Water Oxidation Catalyst with Terminal Water Ligands
The oxomanganese complex [H(2)O(terpy)Mn(III)(μ-O)(2)Mn(IV)(terpy)H(2)O](3+) (1, terpy = 2,2′:6-2″-terpyridine) is a biomimetic model of the oxygen evolving complex of photosystem II with terminal water ligands. When bound to TiO(2) surfaces, 1 is activated by primary oxidants (e.g., Ce(4+)(aq), or...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2010
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2935188/ https://ncbi.nlm.nih.gov/pubmed/20827389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ct1002658 |
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