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Total Synthesis of Fostriecin: Via a Regio- and Stereoselective Polyene Hydration, Oxidation and Hydroboration Sequence

[Image: see text] A total synthesis of the fostriecin has been achieved in 24 steps from enyne 11. The lactone moiety was installed by a Leighton allylation and Grubbs ring-closing metathesis (RCM) reaction. The highly reactive Z,Z,E-triene moiety was installed via a late stage Suzuki-Miyaura cross...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Gao, Dong, O’Doherty, George A.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2010
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2929272/
https://ncbi.nlm.nih.gov/pubmed/20687585
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101340n
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