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An unexpected ‘4+2’ [N(3)S]:[NS] rhenium(IV) complex formed upon cleavage of a Re(V) imido bond

The reaction of [Re(NMe)Cl(3)(PPh(3))(2)] with the pentadentate [N(3)S(2)] ligand pyN(2)H(2)S(2)–H(2) [2,6-bis(2-mercaptophenylamino)dimethylpyridine] (1) in the presence of triethylamine did not yield the anticipated six-coordinate complex [Re(NMe)(η(5)-pyN(2)HS(2))] (2), but rather resulted in cle...

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Bibliografiske detaljer
Main Authors: Chen, Xiaoyuan, Femia, Frank J., Babich, John W., Zubieta, Jon
Format: Artigo
Sprog:Inglês
Udgivet: 2000
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2918897/
https://ncbi.nlm.nih.gov/pubmed/20703331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0020-1693(00)00278-4
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