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An unexpected ‘4+2’ [N(3)S]:[NS] rhenium(IV) complex formed upon cleavage of a Re(V) imido bond
The reaction of [Re(NMe)Cl(3)(PPh(3))(2)] with the pentadentate [N(3)S(2)] ligand pyN(2)H(2)S(2)–H(2) [2,6-bis(2-mercaptophenylamino)dimethylpyridine] (1) in the presence of triethylamine did not yield the anticipated six-coordinate complex [Re(NMe)(η(5)-pyN(2)HS(2))] (2), but rather resulted in cle...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2000
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2918897/ https://ncbi.nlm.nih.gov/pubmed/20703331 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0020-1693(00)00278-4 |
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