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Syntheses and structural characterization of rhenium-bis-hydrazinopyrimidine core complexes with thiolate and Schiff base coligands
The reaction of perrhenate with 2-hydrazinopyrimidine in MeOH–HCl yields [ReCl(3)(η(1)-NNC(4)H(3)N(2)H)(η(2)-HNNC(4)H(3)N(2))] (1). The analogous reaction with Na(2)MoO(4) yields [MoCl(3)(η(1)-NNC(4)H(3)N(2)H)(η(2)-HNNHC(4)H(3)N(2))] (1a). The reaction of 1 with pyrimidine-2-thiol and triethylamine...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2000
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2904462/ https://ncbi.nlm.nih.gov/pubmed/20640229 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0020-1693(00)00287-5 |
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