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Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC–Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones or Thioesters
An efficient Cu-catalyzed method for enantioselective boronate conjugate additions to trisubstituted alkenes of acyclic α,β-unsaturated carboxylic esters, ketones and thioesters is disclosed. All transformations are promoted by 5 mol % of a chiral monodentate NHC–Cu complex, derived from a readily a...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2916754/ https://ncbi.nlm.nih.gov/pubmed/20681680 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104777u |
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