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Synthesis and Conformational Analysis of Bicyclic Extended Dipeptide Surrogates

Regio- and diastereoselective reactions of a homoproline enolate enable the synthesis of novel extended dipeptide surrogates. Bicyclic carbamate 9 and fused β-lactam scaffold 11 were prepared from L-pyroglutamic acid via substrate-controlled electrophilic azidation. Synthesis of orthogonally-protect...

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Detalhes bibliográficos
Main Authors: Ranatunga, Sujeewa, Liyanage, Wathsala, Del Valle, Juan R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2914495/
https://ncbi.nlm.nih.gov/pubmed/20593836
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo1008433
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