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Synthesis of Boc-protected bicycloproline
The synthesis of a highly constrained quaternary carbocyclic α-amino acid, (+)-N-Boc-bicycloproline, has been achieved starting from sodium cyclopentadienylide. Key steps include a rhodium-catalyzed nitrenoid C–H insertion to install the tert-alkylamine and a ring-closing metathesis reaction to form...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2808134/ https://ncbi.nlm.nih.gov/pubmed/20090865 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.03.092 |
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