A Stereoselective Intramolecular Cyclopropanation via a De Novo Class of Push-Pull Carbenes Derived from DMDO-Epoxidations of Chiral Ynamides

This work describes the first examples of diastereoselective intramolecular cyclopropanations of a de novo class of push-pull carbenes derived from DMDO-epoxidations of chiral ynamides. This reaction sequence essentially constitutes a tandem epoxidation–cyclopropanation that effectively gives arise...

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Bibliographic Details
Main Authors: Li, Hongyan, Antoline, Jennifer E., Yang, Jin-Haek, Al-Rashid, Ziyad F., Hsung, Richard P.
Format: Artigo
Language:Inglês
Published: 2010
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2910449/
https://ncbi.nlm.nih.gov/pubmed/20668650
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0nj00063a
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