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A Highly Stereoselective Synthesis of Chiral α-Amino-β-Lactams Via the Kinugasa Reaction Employing Ynamides
A highly stereoselective synthesis of chiral α-amino-β-lactam through an ynamide-Kinugasa reaction is described. In addition, a mechanistic model is illustrated here to rationalize the observed diastereoselectivity, which depends on both the initial [3 + 2] cycloaddition step and the subsequent prot...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , , , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2008
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587087/ https://ncbi.nlm.nih.gov/pubmed/18613692 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801257j |
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