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Molecular Recognition in Mn-Catalyzed C-H Oxidation. Reaction Mechanism and Origin of Selectivity from a DFT Perspective
Experimental studies have shown that the C-H oxidation of ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivies using [(terpy’)Mn(OH(2))(μ-O)(2)Mn(OH(2))(terpy’)](3+) as catalyst, where terpy’ is a terpyridine ligand functionalized with a phenylene linker and a Kemp’s...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2908378/ https://ncbi.nlm.nih.gov/pubmed/19623399 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b905317d |
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