Molecular Recognition in Mn-Catalyzed C-H Oxidation. Reaction Mechanism and Origin of Selectivity from a DFT Perspective

Experimental studies have shown that the C-H oxidation of ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivies using [(terpy’)Mn(OH(2))(μ-O)(2)Mn(OH(2))(terpy’)](3+) as catalyst, where terpy’ is a terpyridine ligand functionalized with a phenylene linker and a Kemp’s...

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Hlavní autoři: Balcells, David, Moles, Pamela, Blakemore, James, Raynaud, Christophe, Brudvig, Gary W., Crabtree, Robert H., Eisenstein, Odile
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2908378/
https://ncbi.nlm.nih.gov/pubmed/19623399
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b905317d
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